Return to balancing half-reactions in acid solution
Here is the half-reaction in acid solution:
Cr2O72¯ ---> Cr3+
Step One: Balance the atom being reduced/oxidized.
Cr2O72¯ ---> 2Cr3+
Step Two: Balance the oxygens.
Cr2O72¯ ---> 2Cr3+ + 7H2O
Step Three: Balance the hydrogens.
14H+ + Cr2O72¯ ---> 2Cr3+ + 7H2O
Step Four: Balance the total charge.
6e¯ + 14H+ + Cr2O72¯ ---> 2Cr3+ + 7H2O