CuS + NO3¯ ---> NO + Cu2+ + HSO4¯
In this reaction, CuS is a solid substance with a nitric acid solution being poured on it. Chemically, both the Cu and the S must be accounted for, but ONLY at the end, in the final answer.
In this problem, we can eliminate the Cu from both sides of the equation and make things a bit simpler. The reason we can do this has to do with what happens to the Cu during the reaction. Note that it is a +2 ion in solution as a product. However, what is its charge in the CuS? The answer is +2, so the Cu was neither reduced nor oxidized in the reaction. That means we can eliminate it during the balancing and act like only S2¯ is in solution. However, we must add the Cu back in at the end.
So, let's the drop the Cu to get:
S2¯ + NO3¯ ---> NO + HSO4¯
the two half-reactions are as follows:
| S2¯ | ---> | HSO4¯ |
| NO3¯ | ---> | NO |
balancing them gives:
| 4H2O + S2¯ | ---> | HSO4¯ + 7H+ + 8e¯ |
| 3e¯ + 4H+ + NO3¯ | ---> | NO + 2H2O |
make the number of electrons equal:
| 3 [4H2O + S2¯ | ---> | HSO4¯ + 7H+ + 8e¯] |
| 8 [3e¯ + 4H+ + NO3¯ | ---> | NO + 2H2O] |
the not so final answer:
| 3 S2¯ + 11H+ + 8NO3¯ | ---> | 3HSO4¯ + 8NO + 4H2O |
put the Cu2+ back in.
| 3 CuS + 11H+ + 8NO3¯ | ---> | 3 Cu2+ + 3HSO4¯ + 8NO + 4H2O |